MONSANTO CO -- ROUNDUP PRO HERBICIDE -- 6840-01-108-9578
===================== Product Identification ===================== Product ID:ROUNDUP PRO HERBICIDE MSDS Date:08/07/1998 FSC:6840 NIIN:01-108-9578 === Responsible Party === Company Name:MONSANTO CO Address:800 N LINDBERGH BLVD City:SAINT LOUIS State:MO ZIP:63167 Country:US Info Phone Num:800-332-3111 Emergency Phone Num:314-694-4000 (CALL COLLECT) Resp. Party Other MSDS Num.:S00012732 CAGE:76541 === Contractor Identification === Company Name:MONSANTO CO, FIBERS BUSINESS UNIT Address:800 N LINDBERGH BLVD Box:City:SAINT LOUIS State:MO ZIP:63167 Country:US Phone:314-694-1000 CAGE:3Y784 Company Name:MONSANTO COMPANY Address:800 N LINDBERGH BLVD Box:City:SAINT LOUIS State:MO ZIP:63167 Country:US Phone:314-694-6661 OR 800-332-3111 CAGE:76541 Company Name:TIMBERLAND ENTERPRISES INC Address:140 ARKANSAS ST Box:557 City:MONTICELLO State:AR ZIP:71655 Country:US Phone:501-367-8561 Contract Num:SP0450-99-M-C397 CAGE:1HB45 ============= Composition/Information on Ingredients ============= Ingred Name:GLYPHOSATE, N-(PHOSPHONOMETHYL) GLYCINE, IN THE FORM OF ITS ISOPROPYLAMINE SALT CAS:38641-94-0 RTECS #:MC1080000 = Wt:41. Other REC Limits:NONE RECOMMENDED Ingred Name:INERT INGREDIENTS (INCLUDING SURFACTANT) = Wt:59. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >5000 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: NOT SPECIFIED BY MANUFACTURER. ACUTE- EYES:MAY CAUSE IRRITATION & PAIN. SKIN: NO MORE THAN SLIGHTLY IRRITATING OR TOXIC BASED ON TOXICITY STUDIES. ORAL: IF LARGE QUANTITES ARE INGESTED, MAY CAUSE HYPOTENTION & LUNG EDEMA. INHALATION: NO MORE THAN SLIGHTLY TOXIC. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: MAY CAUSE PAIN, REDNESS AND TEARING. INGESTION: SIMILAR FORMULATIONS HAVE PRODUCED GASTROINTESTINAL DISCOMFORT WITH IRRITATION OF THE MOUTH, NAUSEA, VOMITING AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. FOR ADDITIONAL HUMAN EMERGENCY FIRST AID OR TREATMENT GUIDANCE, CALL COLLECT, ANYTIME, DAY OR NIGHT (314) 694-4000. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, DRY CHEMICAL OR ANY CLASS B EXTINGUISHING AGENT. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD BE CLEANED AFTER USE. AVOID ENVIRONMENTAL CONTAMINATION. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILLS: < ONE GALLON, SOAK UP WITH TOXELS OR OTHER ABSORBENT MATERIAL & DISCARD IN THE TRASH. CLEAN ARE WITH SOAP & WATER & RINSE THOROUGHLY. LG SPILLS: CONTAIN OR DIKE & THEN ABSORB WITH ATTAPULG ITE, BENTONITE OR OTHER ABSORBENT CLAYS.COLLECT CONTAMINATED ABSORBENT, PLACE IN METAL DRUM & DISPOSE OF IN ACCORDANCE WITH DISPOSAL INSTRUCTIONS. THOROUGHLY SCRUB FLOOR W/ STRONG DETERGENT. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT CONTAMINATE WATER, FOODSTUFFS, FEED OR SEED BY STORAGE OR DISPOSAL. AVOID CONTACT WITH EYES OR CLOTHING. REMOVE CLOTHING IMMEDIATELY IF PESTICIDE GETS INSIDE. THEN WASH THOROUGHLY AND PUT ON CL EAN CLOTHING. Other Precautions:AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING VAPORS/MISTS. WASH THOROUGHLY AFTER HANDLING MATERIAL AND BEFORE EATING OR DRINKING. DO NOT INGEST. EMPTIED CONTAINER RETAINS VAPOR AND PRODUCT RESIDU E. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR HANDLING THE CONC. PRODUCT: IN THE EVENT OF ABNORMAL EXPOSURE CONDITIONS, USE NIOSH/MSHA APPROVED EQUIPMENT. IN WORK SITUATIONS WHERE AN AIR PURIFYING RESPIRATOR IS APPROPRIATE TO BE USED, USE OF A FULL FACE RESPIRATOR EQUIPPED WITH PURIFYING ELEMENTS FOR PROTECTION AGAINST ORGANIC VAPOR AND DUST/MIST APPROVED FOR PESTICIDES IS RECOMMEDED. Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED. Protective Gloves:RUBBER TO AVOID CONTACT Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER, APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN Work Hygienic Practices:DO NOT PERMIT EATING, DRINKING OR SMOKING NEAR THIS MATERIAL. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T5 NRC/State Lic Num:NOT RELEVANT Spec Gravity:1.17 pH:4.99 (!% SOLN) Appearance and Odor:CLEAR, VISCOUS AMBER-COLORED SOLUTION; ODORLESS TO SLIGHT AMINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES GALVANIZED OR UNLINED STEEL, EXCEPT STAINLESS STEEL. Stability Condition to Avoid:STABLE AT LEAST FOR 5 YEARS UNDER NORMAL CONDITIONS OF WAREHOUSE STORAGE. Hazardous Decomposition Products:NONE =================== Toxicological Information =================== Toxicological Information:ORAL RAT LD50 >5000 MG/KG; FIFRA CATEGORY IV. DERMAL RAT DL50 >5000 MG/KG; FIFRA CATEGORY IV. INHALATION RAT LC50 (4 HR EXP.) 4.2 MG/L; FIFRA CATEGORY IV; NOT DOT POISONOUS. EYE IRRITATION RABBIT M ODERATELY IRRITATING; ALL ANIMALS FREEOF IRRITATION BY DAY 7, FIFRA CATEGORY III. SKIN IRRITATION RABBIT (4 HR EXP.) SLIGHTLY IRRITATING; PII 0.63/8.0, ALL ANIMALS FREE OF IRRITATION BY DAY 7, FIFRA CATEGORY IV. ===================== Ecological Information ===================== Ecological:AQUATIC AND AVIAN STUDIES WITH THIS PRODUCT HAVE NOT BEEN CONDUCTED AT THIS TIME. HOWEVER, AN EXTENSIVE DATABASE OF STUDIES EXISTS FOR THE ACTIVE INGREDIENT GLYPHOSATE. THESE STUDIES INDICATE THAT GLY PHOSATE RANGES FROM PRACTICALLY NON-TOXIC TO SLIGHTLY TOXIC IN A VARIETY OF AQUATIC AND AVIAN SPECIES. FOR GLYPHOSATE MSDS OR ADDITIONAL INFORMATION, CONTACT MONSANTO AT 1-800-332-3111. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTES RESULTING FROM THE USE OF THIS PRODUCT THAT CANNOT BE USED OR CHEMICALLY REPROCESSED SHOULD BE DISPOSE OF IN A LANDFILL APPROVED FOR PESTICIDE DISPOSAL OR IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE OR LOCAL PROCEDURES. OBSERVE ALLLABELED SAFEGUARDS UNTIL CONTAINER IS CLEANED, RECONDITIONED OR DESTROYED. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORIES UNDER CRITERIA OF SARA TITLE III RULES (40 CFR PART 370): IMMEDIATE. SECTION 313 TOXIC CHEMICAL(S): NOT APPLICABLE. Federal Regulatory Information:ALL COMPONENTS ARE ON THE US EPA'S TSCA INVENTORY LIST. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.