MALLINCKRODT INC., SCIENCE PRODUCTS DIV. -- ETHYL ALCOHOL DENNATURED -- 6810-00N009079
===================== Product Identification ===================== Product ID:ETHYL ALCOHOL DENNATURED MSDS Date:11/06/1985 FSC:6810 NIIN:00N009079 === Responsible Party === Company Name:MALLINCKRODT INC., SCIENCE PRODUCTS DIV. Address:PARTS BYPASS Box:M City:PARTS State:KY ZIP:40361 Info Phone Num:606-987-7000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Other REC Limits:N/K OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Other REC Limits:N/K OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:KEROSENE.LD50 RABBIT ORAL 28 G/KG.NIOSH 10-HR TWA 100 MG/CUM. CAS:8008-20-6 RTECS #:OA5500000 Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:MAY AFFECT THE NERVOUS SYSTEM.MAY CAUSE LIVER INJURY AND PANCREATITIS.PROLONGED EXPOSURE MAY CAUSE DRYNESS AND CRACKING OF SKIN. Explanation of Carcinogenicity:ETHYL ALCOHOL:CARCIN IN HUMANS NOT DETERMINED,LIMITED NEGATIVE EVIDENCE FOR CARCINOGENICITY IN ANIMALS (GENE-TOX 1987). Effects of Overexposure:EYES:SEV IRRIT.SPLASHES CAUSE TEMPORARY PAIN/BLURRED VISION.SKIN:MAY CAUSE IRRIT.PRLNG CONT MAY PRODUCE DISCOLORATION. INGEST:CAN CAUSE GASTRITIS.VOMIT.CNS DEPRESSION W/ HDACH,DIZZ & DULLNESS.INHAL:EX POS MAY CAUSE IRRIT TO MUC MEMB OF UPPER RESP TRACT.PRLNG EXPOS TO HIGH CONC MAY CAUSE DROWINESS.LOSS OF (SEE SUPP DATA) Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING SKIN DISORDERS,EYE PROBLEMS. OR IMPAIRED KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTE OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/ H*2O FOR AT LEAST 15 MIN,PARTING LIDS OCCASIONALLY.SKIN:WASH SKIN WITH SOAP & H&2O FOR AT LEAST 15 MIN.GET MED ATTN IF IRRIT DEVELOPS/PERSISTS.REMOVE CONTAM CLTHG.INGEST:INDUCE VOMIT IMM ED BY GIVING 2 GLASSES WATER (MILK IF AVAIL ) & STICKING FINGER DOWN THROAT.CALL MD BREATHING.GIVE ARTIFICIAL RESPIRATION.IF BRTHG IS DIFFICULT,GIVE O*2.CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:13C,55F Lower Limits:3.3 BY VOL Upper Limits:19.0% BY VOL Extinguishing Media:DRY CHEMICAL,FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA &FULL PROT EQUIP .USE H*2O TO KEEP FIRE EXPOSED CNTNRS COOL.FLUSH SPILLS AWAY FROM EXPOSURES.& DILUUTE SPILLS TO NON-FLAM MIXT. Unusual Fire/Explosion Hazard:FLAMMABLE.DANGEROUS FIRE HAZ WHEN EXPOSED TO HEAT/FLAMES.ABOVE FL PT.VAP-AIR MIXTURES ARE EXPLO WITHIN FLAM LIM NOTED ABOVE.VAP CAN FLOW ALONG SURF TO (SEE SUP) ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA,REMOVE ALL SOURCES OF IGNIT.CLEAN-UP PERS REQ PROT CLTHG & RESP PROT FROM VAP.CONTAIN & RECOVER LIQ IF POSS.COLLECT AS HAZ WASTE & ATOMIZE IN SUITABLE RERA APPRVD COMBUST CHAMBER/ABSORB W/ V ERMICULITE,DRY SAND,EARTH.DO NOT FLUSH TO SEWER. Neutralizing Agent:N/K ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY WELL-VENT AREA,AWAY FROM FIRE HAZ & 0XIDIZING MATLS.OUTSIDE OR DETACHED STOR IS PREF.STORAGE/USE AREAS SHOULD BE NO SMOKING AREAS. Other Precautions:KEEP AWAY FROM HEAT,SPARKS & FLAME.KEEP CNTNR CLSD.USE W/ ADEQ VENT.AVOID CONT W/ EYES,SKIN & CLTHG.AVOID BRTHG VAP.BOND/GROUND CNTNRS FOR TRANSFERS TO AVOID STATIC SPK.USE NON-SPARKING TOOLS & EQUIP. WARNING:FLAM.HARMFUL IF (SEE SUPP DATA). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV Protective Gloves:RECOMMENDED Eye Protection:CHEMICAL WORKERS GOGGLES Other Protective Equipment:LAB COAT,APRON OR COVERALLS.EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.INSURE PROMPT REMOVAL FROM SKIN.EYES CLOTHING. Supplemental Safety and Health VP: MMHG @ 77F.25C.MPC.MP:<-173F,-114C.FIRE AND EXPLOSION HAZARDS:DISTANT IGNITION SOURCE AND FLASH BACK.AUTOIGNITION TEMP:793F,422C.HAZ DECOMP PROD ARE CO & CO*2.EFTS OF OVEREXPOS:APPETITE & INABILI TY TO CONCENTRATE.OTHER PREC:SWALLOLED/INHALED.DO NOT WEAR CONTACT LENSES ARIUND PROD.ETHAN:RABBIT EYE 100 MG/24 HR SEV. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:172.4F.78C Melt/Freeze Pt:M.P/F.P Text:SEE SUPP Decomp Temp:Decomp Text:N/K Vapor Pres:SEE SUPP Vapor Density:1.6,AIR=1 Spec Gravity:0.80 (WATER=1) Evaporation Rate & Reference:APPROX 3.3 (BUAC=1) Solubility in Water:INFINITE IN WATER. Appearance and Odor:CLEAR,COLORLESS LIQUID;MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND SOURCES OF IGNITION. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE.AVOID HEAT. Hazardous Decomposition Products:MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE WHEN HREATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .DISPOSE IN RCRA APPROVED COMBUSTION CHAMBER. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.