SYSTEM THREE RESINS -- EPOXY PASTE PIGMENTS, 3402-3408 -- 8010-00N082982
===================== Product Identification ===================== Product ID:EPOXY PASTE PIGMENTS, 3402-3408 MSDS Date:10/10/1990 FSC:8010 NIIN:00N082982 === Responsible Party === Company Name:SYSTEM THREE RESINS Address:1155 NW 46TH ST Box:70436 City:SEATTLE State:WA ZIP:98107 Country:US Info Phone Num:206-782-7976 Emergency Phone Num:800-424-9300 (CHEMTREC) Preparer's Name:WKH CAGE:OO286 === Contractor Identification === Company Name:SYSTEM THREE RESINS Address:1155 N W 48TH STREET Box:70436 City:SEATTLE State:WA ZIP:98107 Country:US Phone:206-782-7976 CAGE:OO286 Company Name:SYSTEMS THREE RESINS INC Address:1155 NW 46TH STREET Box:70436 City:SEATTLE State:WA ZIP:98107 Country:US Phone:206-782-7976 CAGE:0N8J4 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE, 1-CHLORO-2,3-EPOXY-; (EPICHLOROHYDRIN) (SARA 302/313) (CERCLA) CAS:106-89-8 RTECS #:TX4900000 Fraction by Wt: <10% PPM OSHA PEL:S, 5 PPM ACGIH TLV:S, 2 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PHENOL, 4,4'-ISOPROPYLIDENEDI-; (4,4'- ISOPROPYLIDENEDIPHENOL) (SARA 313) CAS:80-05-7 RTECS #:SL6300000 Fraction by Wt: <100%PPM OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: 50-75% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PIGMENTS; (TITANIUM DIOXIDE, LAMP BLACK, IRON OXIDE, PHTHALOCYANINE, LEAD (YELLOW), QUINACRADONE PIGMENTS) Fraction by Wt: 50-25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MATERIAL VOLATILE ORGANIC COMPOUND: NONE. RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: VICTIM IS UNCON/VERY DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF WATER & INDUCE VOMIT BY GIVING (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: 2 TABLESPOONS SYRUP OF IPECAC (1 TABLESPOON & 1 GLASS OF WATER FOR CHILD). IF IPECAC IS UNAVAILABLE, GIVE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: 2 GLASSES OF WATER & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF THROAT. KEEP HEAD BELOW HIPS WHILE VOMIT. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: GET MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:DIATOMACEOUS EARTH, SAWDUST, OR OTHER ABSORB, AND SHOVELED INTO DISPOSAL CONTAINERS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: SLIGHTLY IRRITATING TO SKIN, MODERATELY IRRITATING TO EYES. ODOR MAY IRRITATE NOSE, THROAT & RESPIRATORY TRACT OF SOME PERSONS. ORAL INGEST OF ECH MAY CAUSE CNS DEPRESS. CHRONIC: MAY CAUSE SKIN SENSITIATION FROM PROLONGED AND REPEATED CONTACT. LABORATORY ANIMAL STUDIES INDICATE THAT ECH IS A (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CARCINOGEN. CARCIN: EARLY STUDIES W/DGEBPA HAVE BEEN NEG. ECH IS PRESENT IN TRACE AMTS BUT IT IS UNLIKELY THAT NORM WORKING PRACTICES WILL PRDCE ECH CONCS APPROACHING OSHA LIMITS. ECH HAS BE EN SHOWN TO CAUSE CANCER IN LAB ANIMALS. THE IARC STATES THAT EVID THAT ECH CAUSES CANCER IN HUMANS IS INADEQ. (SUPDAT) Medical Cond Aggravated by Exposure:OTHER THAN SKIN SENSITIZATION WHICH APPEARS TO BE PERMANENT, EPOXY RESIN DOES NOT APPEAR TO CAUSE LONG TERM HEALTH EFFECTS. NOR, DOES IT APPEAR TO AGGRAVATE OTHER MEDICAL CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR @ LST 15 MINS HOLDING EYELIDS OPEN. SEEK MED ATTN. SKIN: REMOVE CONTAMD CLTHG & SHOES & WIPE EXCESS OFF SKIN. FLUSH W/WATER. FOLLOW BY WASHING IN SOAP & WATER. IF IRRIT OCCURS, SEEK MED ATTN. DO NOT REUSE CLTHG UNTIL CLEANED. CONTAMD LEATHER ARTICLES (SHOES) CAN NOT BE DECONTAMD & SHOULD BE DESTROYED. INHAL: REMOVE VICTIM TO FRESH AIR & PROVIDE OXYG IF BRTHG IS (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>350F,>177C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROTECTIVE EQUIP . WATER SPRAY MAY BE USED TO COOL FIRE EXPOS CNTNRS. TOXIC FUMES MAY BE EVOLVED WHEN THIS SUBSTANCE IS BURNED. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONT W/MATL. PERSONS NOT WEARING APPROP PROT EQUIP SHOULD LEAVE AREA OF SPILL UNTIL CLEANUP IS COMPLETE. STOP SPILL AT SOURCE, DIKE AREA TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK OR DRUM . REMAINING LIQ MAY BE TAKEN UP ON CLAY, (ING 10) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NONE IS REQUIRED WHEN ADEQUATE VENT IS PROVIDED. IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL NIOSH APPRVD RESPIRATORY IS REQUIRED. FOR EMERGENCIES, A NIOSH APPRVD SCBA OR NIOSH APPRVD FULL-FAC ED RESPIRATOR IS RECOMMENDED. Ventilation:PROVIDE ADEQUATE VENTILATION IN WORK AREAS. CONFINE MATERIAL IS SEALED CONTAINERS WHEN NOT IN USE. Protective Gloves:IMPERVIOUS, NEOPRENE, VINYL/RUBB GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR CLEAN, BOYD-COVERING TO AVOID SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health CNDTNS TO AVOID: UNDER UNCONTROLLED CNDTNS/IN LG MASS AS ENSURING EXOTHERM MAY RSLT IN HEAT & SMOKE RSLTG IN HAZ DECOMP PRODS. EFTS OF OVEREXP: THE IARC CONCLUDED IN 1988 THAT DGEBPA WAS NOT CLASSIFIA BLE AS A CARCIN. FIRST AID PROC: DFCLT.GIVE ARTF RESP IS NOT BRTHG. GET MED ATTN. INGEST: DO NOT GIVE LIQS IF (ING 6) ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.10 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:THICK COLORED DISPERSIONS OF PIGMENTS IN EPOXY RESIN - NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, LEWIS AND MINERAL ACIDS. Stability Condition to Avoid:EXPOXY RESINS & EPOXY RESIN HARDENERS REACT W/EACH OTHER PRODUCING HEAT. THEY SHOULD NOT BE MIXED W/EACH OTHER (SUPDAT) Hazardous Decomposition Products:OXIDES OF CARBON, ALDEHYDES, ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE IS NOT HAZARDOUS BY RCRA CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.