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                | (000000-000000-    - 5068) |  
                | Date of Issue: 12/21/2007 12:00:00 AM
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 | Supercedes: 12/21/2007 12:00:00 AM
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                | Chemical Name & 
                  Synonyms: N/A
 | 
 | Trade Name & 
                  Synonyms: FREE 
                  W/MOLY AEROSOL
 |  
                | Chemical Family: Petroleum distillate 
                  mixture
 | 
 | Formula is a 
                  mixture: [√] |  
                | Manufacturer Name: CERTIFIED LABS, DIV. OF NCH 
                  CORP.
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                | Manufacturer 
                  Address: BOX 152170
 IRVING, TEXAS 75015
 
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                | Prepared By: M MCDOWELL/CHEMIST
 | Product Code Number: 5068
 | Emergency Phone 
                  Number: 800-424-9300
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                | THE HAZARDS PRESENTED BELOW ARE THOSE OF THE 
                  INDIVIDUAL COMPONENTS |  
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                |  |  |  |  |  
                | Boiling Point (°F): | 160-203 | Specific Gravity 
                  (H20=1): | 0.84 |  
                | Vapor Pressure (mm Hg): | 1546 | Color: | Amber-dark amber |  
                | Vapor Density (Air=1): | 1.7 | Odor: | Petroleum/vinegar |  
                | pH @ 100% : | N/A | Clarity: | Transparent |  
                | % Volatile by Volume: | 75 | Evaporation Rate (BuAc=1): | 24.8 |  
                | H20 Solubility: | Negligible | Viscosity: | Non-Viscous |  
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                      | Flash Point: | <80°F | Method Used: | Seta-flash |  
                      | Flammable Limits: | Product mixture | UEL: | 11.5% |  
                      | LEL: | 0.5% | Aerosol Level (NFPA 
                        30B): | 3 |  |  
                |  |  
                | Special Fire Fighting 
                  Procedures: Firefighters should wear a self-contained breathing 
                  apparatus and full protective gear. Cool fire-exposed 
                  containers with water spray to prevent 
              bursting. |  
                | Unusual Fire and Explosion 
                  Hazards: Vapors are heavier than air and may 
                  travel to distant and/or low-lying sources of ignition and 
                  flashback. Product may produce a floating fire hazard as 
                  liquid floats on water. Flame extension is >18 inches, 
                  burnback is >3 inches. Use care as spills may be 
                  slippery. |  |  
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                | Threshold 
                  Limit Value: 
 Not Established for Mixture. See Section 
              II. |  
                | Effects 
                  of Overexposure: |  
                | Acute: (Short Term 
                  Exposure) 
 EYE CONTACT: Causes irritation seen as stinging, tearing, 
                  redness, and a burning sensation. Prolonged contact may cause 
                  conjunctivitis.SKIN CONTACT: Causes irritation seen as 
                  itching and redness. Product may be absorbed through the skin 
                  in harmful amounts. Injection under the skin, in muscle, or 
                  into the blood stream can cause irritation, inflammation, 
                  swelling, fever, and systemic effects, and mild central 
                  nervous system depression. Injection of pressurized 
                  Hydrocarbons can cause severe, permanent tissue damage. 
                  Initial symptoms may be minor. Prolonged or repeated contact, 
                  as from clothing wet with material, may cause drying, 
                  defatting, and cracking of the skin.
 INHALATION: May cause 
                  respiratory irritation seen as coughing and sneezing. At low 
                  vapor concentrations, no harmful effects are expected. At high 
                  vapor concentrations, inhalation may cause central nervous 
                  system effects such as headache, dizziness, drowsiness, 
                  weakness, unconciousness, possible anesthetic effects from 
                  central nervous system depression, and may be 
                  fatal.
 INGESTION: May cause irritation with possible 
                  nausea, vomiting, and diarrhea. May cause central nervous 
                  system effects similar to inhalation. Ingestion and subsequent 
                  vomiting of this product can lead to aspiration of the product 
                  into the lungs which can cause damage and may be 
                  fatal.
 |  
                | Chronic: (Long Term 
                  Exposure) This product has a 
                  narcotic and Central Nervous System depressive effect. May 
                  cause Kidney and Liver congestion in high concentrations. May 
                  cause anemia, edema, leukocytosis, and a degeneration of the 
                  viscera fats. Prolonged exposure is associated to bronchitis, 
                  hepatic, renal, and cardiac damages, and blood alterations. On 
                  rare occasions, prolonged and repeated exposure to hydrocarbon 
                  or oil mist poses a risk of chronic lung inflammation. This 
                  condition is usually asymptomatic as a result of repeated 
                  small aspirations. Shortness of breath and coughing are the 
                  most common symptoms. Aspiration may lead to pulmonary edema 
                  and hemorrhage, and may be fatal. Signs of lung involvement 
                  include increased respiration and heart rates as well as a 
                  bluish discoloration of the skin. Chronic skin contact may 
                  promote dermatitis and oil acne. In rarer cases, an increased 
                  senstivity to sunlight (photosensitivity) may 
                  occur.
 Medical conditions aggravated by exposure are 
                  pre-existing respiratory and skin conditions such as asthma, 
                  emphysema, and dermatitis;  Pre-existing Blood, Liver, 
                  and Kidney diseases.
 TARGET ORGANS: Central nervous system, 
                  heart, liver, lungs, and kidneys. The primary routes of 
                  exposure are skin and eye contact.
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                    |  
                | Emergency 
                  First Aid Procedures: |  
                | Inhalation: 
 Remove from the area to fresh air. Seek medical attention 
                  if respiratory irritation develops or if breathing becomes 
                  difficult. |  
                | Eye Contact: 
 Rinse the eyes with water. Remove any contact lenses and 
                  continue flushing with plenty of water for several minutes. 
                  Seek medical attention if irritation 
develops. |  
                | Skin Contact: 
 Wash affected areas with large amounts of soap and water 
                  for 15 minutes. Remove contaminated clothing and shoes. Seek 
                  medical attention if irritation persists. Wash clothing and 
                  clean shoes before re-use. |  
                | Ingestion: 
 Give 3 to 4 glasses of water, but DO NOT induce vomiting. 
                  If vomiting occurs, give fluids again. Get immediate medical 
                  attention. Do not give anything by mouth to an unconscious or 
                  convulsing person. |  
                | Notes to Physician: 
 Ingestion and subsequent vomiting of this product can lead 
                  to aspiration of the product into the lungs which can cause 
                  damage and may be fatal. Depending on the amount ingested and 
                  retained as well as the toxicity of the product, gastric 
                  lavage should be considered. Keep patient's head below hips to 
                  prevent pulmonary aspiration. If comatose, a cuffed 
                  endotracheal tube will prevent aspiration. In the event of 
                  injection in underlying tissue, immediate treatment should 
                  include extensive incision, debridement and saline irrigation. 
                  Inadequate treatment can result in ischemia and gangrene. 
                  Early symptoms may be 
            minimal. |  |  
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                | ALIPHATIC PETROLEUM 
                  DISTILLATES ORL-RAT LD50: >5,000 
                  mg/kg     3.
 SKN-RBT LD50: 
                  >3,160 mg/kg     3.
 IHL-RAT 
                  LC50: >5.2 
                  mg/L/4 hr     5.
 SKN-RBT: 
                  Moderate irritation     
                  3.
 EYE-RBT: Mild irritation    
                   3.
 
 
 
 Similar 
                  materials were administered orally 5 days/week to male 
                  and female rats at 100, 500 or 1000 mg/kg for 13 weeks. An 
                  additional group was dosed with 100 mg/kg for 13 weeks 
                  followed by a 4-week recovery period. No mortalities or 
                  clinical effects were observed. Liver and kidney weights for 
                  the 500 and 1000 mg/kg exposure groups were significantly 
                  increased. After the 4-week recovery period, there were no 
                  differences in organ weights.     
                  3.
 Animal data suggest that slight anemia, adaptive 
                  liver changes, and kidney toxicity may be caused by repeated 
                  overexposure to some similar solvents. The significance of 
                  this to humans is unknown.     
                  3.
 
 Hydrocarbon mists derived from highly refined 
                  petroleum distillates are reported to have low acute and 
                  sub-acute toxicities in animals. Effects from single and 
                  short-term repeated exposures to high concentrations well 
                  above applicable workplace exposure levels include lung 
                  inflammatory reaction, lipoid granuloma formation, and lipoid 
                  pneumonia. In acute and sub-acute studies involving exposures 
                  to lower concentrations at or near current work place exposure 
                  levels produced no significant toxicological effects. In long 
                  term studies (up to two years) no carcinogenic effects have 
                  been reported in any animal species tested. These petroleum 
                  distillates are severely hydrotreated, severely solvent 
                  extracted, and/or processed by mild hydrotreatment and 
                  extraction. For this reason, they are not classified as cancer 
                  hazards.     3.
 
 ETHYL ACETATE
 EYE-HMN SDT: 
                  400 ppm                                              
                  4.
 IHL-HMN TCLo: 
                  400 ppm                                             
                  4.
 ORL-RAT LD50: 5,620 
                  mg/kg                                       
                    3.
 IHL-RAT LC50: 16,000 
                  ppm/6h                          
                              
                  3.
 SKN-RBT LD50: >20 mL/kg 
                                                      
                        4.
 SKN-RBT LS50: 
                  >18,000 
                  mg/kg                     
                                  3.
 INH-RAT 
                  LC50: 200 
                  gm/m3                           
                                   
                  4.
 
 SODIUM SULFONATE
 ORL-RAT LD50: 
                  >5,000 mg/kg     3.
 SKN-RAT 
                  LD50: >2,000 mg/kg     
                  3.
 
 HYDROTREATED 
                  LIGHT NAPHTHENIC PETROLEUM DISTILLATE
 ORL-RAT 
                  LD50: >5 g/kg 3.
 SKN-RBT LD50: >3 g/kg 3.
 SKN-RBT IRRITATION 
                  <0.5/8.0; no appreciable effect 3.
 EYE-RBT IRRITATION <15/110; no 
                  appreciable effect 3.
 
 PROPANE
 IHL-LC50 
                  >40% by volume 4.
 
 N-BUTANE
 IHL-RAT 
                  LC50: 658 g/m3/4h 3.
 
 Human 
                  volunteers exposed repeatedly to gases of similar hydrocarbon 
                  mixtures ranging from 250 to 1000 ppm exhibited no cardiac or 
                  pulmonary function abnormalities. 3.
 
 SYNTHETIC 
                  ISOPARAFFINIC HYDROCARBON (<3% DMSO 
                  extractables)
 IHL-RAT LC50: >290 ppm 
                  3.
 ORL-RAT LD50: >10 g/kg 3.
 SKN-RBT 
                  LD50: >3 g/kg 3.
 SKN SENSITIZER: no 
                  3.
 SKN IRRITATION: slight 3.
 EYE IRRITATION: slight 
                  3.
 
 This hydrocarbon was administered orally 5 days/week 
                  to male and female rats at 100, 500 or 1000 mg/kg for 13 
                  weeks. An additional group was dosed with 100 mg/kg for 13 
                  weeks followed by a 4-week recovery period. No mortalities or 
                  clinical effects were observed. Liver and kidney weights for 
                  the 500 and 1000 mg/kg exposure groups were significantly 
                  increased. After the 4-week recovery period, there were no 
                  differences in organ weights. 3.
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                | Incompatibility (Materials to 
                  Avoid): 
 Strong oxidizing agents such as 
                  Chlorine bleach and concentrated Hydrogen Peroxide; 
                  Chlorosulfonic Acid, Lithium Aluminum Hydride, 
                  2-Chloromethylfuran, Lithium Tetrahydroaluminate, Oleum, 
                  Potassium T-Butoxide, Nitric Acid, Perchloric Acid, Chromium 
                  Trioxide, Chlorosulfonic Acid, Silica Gel, Alumina, Nitrates, 
                  Amines, strong Acids and Bases. |  
                | Hazardous Decomposition 
                  Products: 
 Oxides of Carbon, Potassium, and, Nitrogen; Aldehydes, 
                  Molybdenum, alkylmercaptans, dialkylsulfides, and Hydrogen 
                  Sulfides. |  |  
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                | Steps to be Taken if Material is 
                  Released or Spilled: 
 Due to the nature of the packaging, a large spill is 
                  unlikely. For a small spill, absorb with a damp cloth and 
                  rinse area into a sanitary sewer. Use care as spills may be 
                  slippery. |  
                | Waste Disposal 
                  Method(s): 
 Dispose of in accordance with all Federal, state, and local 
                  regulations. Typical disposal is to wrap the empty aerosol 
                  container in several layers of newspaper and dispose of in the 
                  trash. Aerosol recycling programs are available in many areas. 
                  Do not puncture or incinerate this container. |  
                | Neutralizing Agent: N/A
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                | Required 
                  Ventilation: 
 Local ventilation is recommended to control exposure from 
                  operations that can generate excessive levels of mists or 
                  vapors. Local ventilation is preferred, because it prevents 
                  dispersion into work areas by controlling it at its 
                  source. |  
                | Respiratory 
                  Protection: 
 Respirators should be selected by and used under the 
                  direction of a trained health and safety professional 
                  following requirements found in OSHA's respirator standard (29 
                  CFR 1910.134) and ANSI's standard for respiratory protection 
                  (Z88.2-1992). For concentrations above the TLV and/or PEL but 
                  less than 10 times these limits, a NIOSH approved 
                  half-facepiece respirator equipped with appropriate chemical 
                  cartridges may be used. For concentrations greater than 10 
                  times the TLV and/or PEL, consult the NIOSH respirator 
                  decision logic found in publication No. 87-116 or ANSI 
                  Z88.2-1992. |  
                | Glove Protection: 
 Neoprene or nitrile rubber gloves should be 
                  worn. Ensure compliance with OSHA's personal protective 
                  equipment (PPE) standard for hand protection, 29 CFR 
                  1910.138. |  
                | Eye Protection: 
 Safety glasses with side shields if the method of 
                  application presents the likelihood of eye contact. Ensure 
                  compliance with OSHA's Personal Protective Equipment (PPE) 
                  standard for eye and face protection, 29 CFR 
                  1910.133. |  
                | Other Protection: 
 Wear protective clothing when handling. Wash clothing 
                  and clean shoes before re-use. A safety shower and an eyewash 
                  station should be 
            available. |  |  
          | 
 Section X - 
            Storage and Handling Information  
            
              
              
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                | Precautions to be Taken in Handling 
                  and Storing: 
 Use with caution around heat, sparks, pilot lights, static 
                  electricity, and open flame. |  
                | Other Precautions: 
 Keep out of reach of children. Read the entire label before 
                  using the product. Follow the label 
              directions. |  |  
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                | 
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                | Those 
                  Ingredients listed above are subject to the reporting 
                  requirements of 313 of Title III of the Superfund Amendments 
                  and Reauthorization Act of 1986 and 40 CFR part 
              372. |  
                |  |  
                | Please call 
                  1-800-527-9919 for additional information if you are a 
                  California customer. This MSDS is not intended for users in 
                  the state of California. |  
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                      | 1. Threshold Limit Values for chemical substances and 
                        physical agents and biological exposure indices, ACGIH, 
                        2007.2. OSHA PEL.
 3. Vendor's MSDS.
 4. 
                        Registry of toxic effects of chemical substances, 
                        CCINFOWeb, 2007.
 5. European Chemical Substances 
                        Information System (ESIS), International Uniform 
                        Chemical Information Database (IUCLID) Chemical Data 
                        Sheets.
 6. ChemADVISOR, Inc. Database Release: 
                        2007-4.
 All the components of this product are in 
                        compliance with the Toxic Substances Control Act (TSCA) 
                        and are either listed on the TSCA inventory or otherwise 
                        exempted from 
                        listing.
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 IRR: 
                        Irritant, OSHA: Occupational Safety & Health 
                        Administration, IARC: International Agency for the 
                        Research on Cancer, TOX: Toxic, NFPA: National Fire 
                        Protection Association, ppm: Parts Per Million, UEL: 
                        Upper Explosion Limit, STEL: Short-term Exposure Limit, 
                        HMN: Human, mg/m3, IHL: Inhalation, COMB: Combustible, 
                        CORR: Corrosive, MUT: Mutagenic, CARC: Carcinogenic, 
                        N/A: Not Applicable, TLV: Threshold Limit Value, N/E: 
                        Not Established, ORL: Oral, FLAM: Flammable, ASPHYX: 
                        Asphyxiant, C.O.C.: Cleveland Open Cup, PNOR: Particles 
                        Not Otherwise Regulated, LEL: Lower Explosion Limit, 
                        mg/L: Milligrams per Liter, PNOS: Particles Not 
                        Otherwise Specified, g/L: Grams per Liter, PMCC: 
                        Pensky-Martin Closed Cup, NTP: National Toxicology 
                        Program, µg/L: Micrograms per Liter, TCC: Tagliabue 
                        Closed Cup, SEV: Severe, RBT: Rabbit, INV: Intravenous, 
                        ACGIH: American Conference of Governmental Industrial 
                        Hygienists, PEL: Permissible Exposure Limit, MOD: 
                        Moderate, IPT: Intraperitoneal, gm/kg: Grams per 
                        Kilogram, C.C.C.: Cleveland Closed Cup, SKN: Skin, 
                        Milligrams per Cubic Meter, mg/kg: Milligrams per 
                        Kilogram, VOC: Volatile Organic Compound, SDT: Standard 
                        Draize Test, MSE: Mouse, GPG: Guinea 
                    Pig.
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